Laboratory Preparations of Chlorine Dioxide Solutions ~OxyChem
****!!!!**** {Instructions for preparing solutions} "Method I produces a material equivalent to that produced by most commercial chlorine dioxide generators. Method II produces a reagent grade, chlorine dioxide solution with no free chlorine and is used for instrument standards and for studies where free chlorine would interfere." "to prepare low concentration (1000 ppm), chemically pure, chlorine dioxide solutions... Chlorine dioxide (ClO2) is produced by the acidification of sodium chlorite (NaClO2) solution with sulfuric acid (H2SO4):
4NaClO2 + 2H2SO4 ---- 2ClO2 + HCl + HClO3 + 2Na2SO4 + H2O
Chlorine dioxide is removed from the reaction flask solution as gas by air stripping, purified by scrubbing with sodium chlorite solution and recovered by absorbing in chilled deionized (DI)
water."